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991.
Daniela Schlemmer E. R. de Oliveira M. J. Araújo Sales 《Journal of Thermal Analysis and Calorimetry》2007,87(3):635-638
Conventional plastics has a
large impact in increasing the environment’s pollution. That’s
why the interest has turned towards novel partially and completely biodegradable
polymers. In this work, blends of polystyrene and thermoplastic starch with
glycerol and Buriti (Mauritia flexuosa
L.) oil as plasticizers were prepared. Samples were analyzed using TG/DTG
and DSC techniques. The TG results indicated that the blends with Buriti oil
are thermally more stable than those with glycerol. The DSC analysis that
Buriti oil provides a higher degree of plasticization of PS, compared to the
blends plasticized using glycerol under the studied conditions. 相似文献
992.
993.
A novel 14-membered macrocyclic Schiff base derived from 3-cinnamalideneacetoacetanilide and o-phenylenediamine acts as a tetradentate and strongly conjugated ligand to form a cationic solid complex with CuCl2/NiCl2/CoCl2/ZnCl2. The ligand and the complexes were characterized by the usual spectral and analytical techniques. The main i.r. band of the macrocyclic Schiff base was compared to that of its metal complexes. The C=N bands are shifted to the lower wave number. The cyclic voltammogram of the copper complex shows that the macrocyclic ligand is able to stabilize the copper(III) oxidation state. The e.s.r. spectra of the copper complex in DMSO solution at room temperature and liquid N2 temperature were recorded and their salient features thoroughly discussed. The antimicrobial screening tests were also recorded and gave good results in the presence of metal ions in the ligand system. 相似文献
994.
Jaime González Velasco 《Central European Journal of Chemistry》2005,3(3):470-481
The analytical treatment of a model considering the electrooxidation of p-porous silicon layers under galvanostatic conditions
is able to give account of experimental facts such as the shape and location of the electroluminescence peak as well as of
the spectral shift of the electroluminescence peak produced by oxidation. The proposed model considers electroluminescence
to be the result of electron injection into the conduction band by an adsorbed intermediate produced by electrooxidation of
the surface coverage with hydrogen or siloxene of the silicon nanocrystallites. The access of holes to the surface is made
possible by low accumulation layer conditions and is the rate determining step in the electroluminescence mechanism. In this
way it is possible to give a satisfactory explanation to the shift towards the blue experimented by the electroluminiscence
emission maximum as a consequence of electrooxidation. 相似文献
995.
V. V. Barbakadze E. P. Kemertelidze I. Targamadze K. Mulkidzhanyan J. Kemink A. J. J. van den Berg K. J. Beukelman A. I. Usov 《Chemistry of Natural Compounds》2005,41(4):374-377
Two high-molecular-weight (>1000 kDa) water-soluble preparations were isolated from stems of Symphytum asperum and S. caucasicum. Their basic component was established as poly[hydroxy-1-carboxy-2-(3,4-dihydroxyphenyl)ethylene], analogous to that of high-molecular-weight
(>1000 kDa) preparations from roots of these same plants, using IR and NMR spectral data.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 303–305, July–August, 2005.
An erratum to this article is available at . 相似文献
996.
Competitive binding of a Tris run buffer with chiral crown ether in chiral capillary electrophoresis
In capillary electrophoresis of primary amine racemates using (+)-(18-crown-6)-tetracarboxylic acid (18C6H4) as a chiral selector, chiral recognition emanates from the differences in the complex formation between 18C6H4 and the two protonated amine enantiomers. The presence of buffer constituents such as tris(hydroxymethyl)aminomethane (Tris) or Na+, capable of forming complexes with 18C6H4, is thus detrimental to the chiral separation of primary amines. Such a competitive binding of buffer constituents was studied by comparing the electrophoretic mobilities of racemic analytes obtained in Tris/citric acid and triethylamine/citric acid buffers. We developed a simple fitting method to determine the competitive binding constant and applied it to the Tris buffer system. The competitive binding constant of Tris with 18C6H4 obtained at pH 3.0 was 27 +/- 4. 相似文献
997.
Stephen de Mora Jean-Pierre Villeneuve Eric Wyse 《Accreditation and quality assurance》2007,12(11):587-592
Aspects of the International Atomic Energy Agency (IAEA) Analytical Quality Control Services (AQCS) for marine environmental
studies are discussed, focusing on recent laboratory performance studies (LPS) and the production of reference materials for
trace metals and organic compounds in various marine matrices. The IAEA has organized seventeen global interlaboratory studies
for a range of organic contaminants. Of note has been the inclusion of numerous polychlorinated biphenyl congeners (PCBs)
and some sterols of anthropogenic origin. Concurrently, there have been eleven worldwide intercomparison exercises for trace
metals in the marine environment, most of which included methylmercury. Although such interlaboratory studies can help improve
performance in individual laboratories and regional laboratory networks, the results reveal that problems remain in the determination
of some metals and many organic contaminants. 相似文献
998.
Summary. An efficient direct conversion of THP ethers into the corresponding acetates was achieved with acetic anhydride in the presence of CuSO4 · 5H2O as an available and green catalyst in high yields. 相似文献
999.
The use of fenugreek mucilage, a natural polysaccharide and a direct food additive, as a flocculating agent for removal of suspended and dissolved solids from sewage effluent has been reported. A flocculation study has been done by the standard jar test method. The percent removal of suspended solid (SS) and dissolved solid (TDS) was determined by varying the polymer dose, pH and contact time. X-ray diffraction patterns of the solid waste material of mucilage and flocs (so obtained after treatment) were used to suggest the incorporation of the crystalline waste material in the mucilage. The optimal mucilage concentration was found to be 0.16 mg/l. The suitable pH range for maximum solid removal (SS and TDS) was alkaline and the time required for treatment was 1-3 h. 相似文献
1000.
Jung SY Lim SM Albertorio F Kim G Gurau MC Yang RD Holden MA Cremer PS 《Journal of the American Chemical Society》2003,125(42):12782-12786
The molecular level details of the displacement of surface adsorbed fibrinogen from silica substrates were studied by atomic force microscopy, immunochemical assays, fluorescence microscopy, and vibrational sum frequency spectroscopy. The results showed that human plasma fibrinogen (HPF) can be readily displaced from the interface by other plasma proteins near neutral pH because the positively charged alpha C domains on HPF sit between the rest of the macromolecule and the underlying surface. The alpha C domains make weak electrostatic contact with the substrate, which is manifest by a high degree of alignment of Lys and Arg residues. Upon cycling through acidic pH, however, the alpha C domains are irreversibly removed from this position and the rest of the macromolecule is free to engage in stronger hydrogen bonding, van der Waals, and hydrophobic interactions with the surface. This results in a 170-fold decrease in the rate at which HPF can be displaced from the interface by other proteins in human plasma. 相似文献